Perviolaris, Alexandros and Stoumpos, Constantinos and Karpinska, Jolanta and Ryder, Alan and Frost, Jamie and Mason, Kevin and Prescimone, Alessandro and Slawin, Alexandra M.Z. and Kessler, Vadim and Mathieson, Jennifer and Cronin, Leroy and Brechin, Euan K. and Papaefstathiou, Giannis S.
(2014).
A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation.
Inorganic Chemistry Frontiers. 1
:6
, 487-494
[Research article]
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Abstract
A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-2− species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.
| Authors/Creators: | Perviolaris, Alexandros and Stoumpos, Constantinos and Karpinska, Jolanta and Ryder, Alan and Frost, Jamie and Mason, Kevin and Prescimone, Alessandro and Slawin, Alexandra M.Z. and Kessler, Vadim and Mathieson, Jennifer and Cronin, Leroy and Brechin, Euan K. and Papaefstathiou, Giannis S. | ||||
|---|---|---|---|---|---|
| Title: | A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation | ||||
| Series Name/Journal: | Inorganic Chemistry Frontiers | ||||
| Year of publishing : | 2014 | ||||
| Volume: | 1 | ||||
| Number: | 6 | ||||
| Page range: | 487-494 | ||||
| Number of Pages: | 8 | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 2052-1553 | ||||
| Language: | English | ||||
| Publication Type: | Research article | ||||
| Refereed: | Yes | ||||
| Article category: | Scientific peer reviewed | ||||
| Version: | Accepted version | ||||
| Full Text Status: | Public | ||||
| Subjects: | (A) Swedish standard research categories 2011 > 1 Natural sciences > 104 Chemical Sciences > Inorganic Chemistry (A) Swedish standard research categories 2011 > 1 Natural sciences > 106 Biological Sciences (Medical to be 3 and Agricultural to be 4) > Biochemistry and Molecular Biology | ||||
| Keywords: | inorganic chemistry, thermal stability, [Ni8] cages, dioxygen activation | ||||
| URN:NBN: | urn:nbn:se:slu:epsilon-e-3130 | ||||
| Permanent URL: | http://urn.kb.se/resolve?urn=urn:nbn:se:slu:epsilon-e-3130 | ||||
| Additional ID: |
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| ID Code: | 11655 | ||||
| Faculty: | NJ - Fakulteten för naturresurser och jordbruksvetenskap | ||||
| Department: | (NL, NJ) > Dept. of Chemistry (until 131231) | ||||
| Deposited By: | SLUpub Connector | ||||
| Deposited On: | 11 Dec 2015 08:07 | ||||
| Metadata Last Modified: | 09 Sep 2020 14:16 |
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