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A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation

Perviolaris, Alexandros and Stoumpos, Constantinos and Karpinska, Jolanta and Ryder, Alan and Frost, Jamie and Mason, Kevin and Prescimone, Alessandro and Slawin, Alexandra M.Z. and Kessler, Vadim and Mathieson, Jennifer and Cronin, Leroy and Brechin, Euan K. and Papaefstathiou, Giannis S. (2014). A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation. Inorganic Chemistry Frontiers. 1:6, 487-494
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Abstract

A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-2− species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Authors/Creators:Perviolaris, Alexandros and Stoumpos, Constantinos and Karpinska, Jolanta and Ryder, Alan and Frost, Jamie and Mason, Kevin and Prescimone, Alessandro and Slawin, Alexandra M.Z. and Kessler, Vadim and Mathieson, Jennifer and Cronin, Leroy and Brechin, Euan K. and Papaefstathiou, Giannis S.
Title:A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation
Series/Journal:Inorganic Chemistry Frontiers (2052-1553)
Year of publishing :2014
Volume:1
Number:6
Page range:487-494
Number of Pages:8
Publisher:Royal Society of Chemistry
ISSN:2052-1553
Language:English
Publication Type:Journal article
Refereed:Yes
Article category:Scientific peer reviewed
Version:Accepted version
Full Text Status:Public
Subjects:(A) Swedish standard research categories 2011 > 1 Natural sciences > 104 Chemical Sciences > Inorganic Chemistry
(A) Swedish standard research categories 2011 > 1 Natural sciences > 106 Biological Sciences (Medical to be 3 and Agricultural to be 4) > Biochemistry and Molecular Biology
Keywords:inorganic chemistry, thermal stability, [Ni8] cages, dioxygen activation
URN:NBN:urn:nbn:se:slu:epsilon-e-3130
Permanent URL:
http://urn.kb.se/resolve?urn=urn:nbn:se:slu:epsilon-e-3130
Additional ID:
Type of IDID
DOI10.1039/C4QI00048J
ID Code:11655
Faculty:NJ - Fakulteten för naturresurser och jordbruksvetenskap
Department:(NL, NJ) > Dept. of Chemistry (until 131231)
Deposited By: SLUpub Connector
Deposited On:11 Dec 2015 08:07
Metadata Last Modified:07 Feb 2016 17:57

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